Feasibility analysis of membrane reactors – discovery of reactive arheotropes

A feasibility analysis methodology adopted from reactive distillation is applied to membrane reactors. A model is formulated to depict the reactive liquid phase composition on the retentate side of a continuous type membrane reactor. The effects of both the chemical reaction kinetics and the membrane mass transfer kinetics on the feasible products are elucidated by means of retentate phase diagrams and bifurcation analysis. The proposed method can be applied to various membrane processes, independent of the specific structure of the membrane. Two quaternary reaction systems are considered to illustrate the methodology. In the first hypothetical system, it is shown how selective membranes can influence the sequence of effective volatilities which in turn affects the feasible products of the system. In the second example of practical importance, i.e. the heterogeneously catalysed synthesis of propyl acetate coupled with permeation through a porous polycarbonate membrane, the dusty gas model is applied to describe the component fluxes through the membrane. For the latter reaction system, the existence of reactive arheotrope is demonstrated. Arheotropes represent mass transfer controlled feasible products of membrane separation process.     

锌电积的节电探讨

分析厂影响锌电积电能消耗的因素，提出了锌电积的节电对策与展望。     

Phase behavior in liquid crystallization for diblock copolymers consisting of rubbery amorphous and side-chain liquid crystalline components

Phase behavior in liquid crystallization was studied for a series of liquid crystalline (LC) diblock copolymers consisting of rubbery amorphous and side-chain liquid crystalline components, poly(n-butyl acrylate) (PBA) and poly[11-(4′-cyanophenyl-4″-phenoxy)undecyl acrylate] (PLC), respectively, using a time-resolved small-angle X-ray scattering (SAXS) techniques, DSC and polarized optical microscopy (POM). The block copolymers used had three kinds of copolymer compositions, 44, 20 and 15 wt% of PLC compositions (BLC44, BLC20 and BLC15, respectively). BLC44 showed a smectic liquid crystalline structure. In the process of liquid crystallization for BLC44, the SAXS peak due to the microphase separation structure existing before liquid crystallization was changed continuously to be at a smaller angular side, and at almost the same time, a new peak appeared at a further smaller angular side and developed. The former peak disappeared with the development of liquid crystallization. The behavior of these SAXS peaks suggests that the microphase separation structure was changed discretely at the transition from isotropic to smectic and that two phases coexist in the early stage of the liquid crystallization. The coexistence of two peaks in the early stage of the liquid crystallization corresponded to the POM observation. In the isotropization process, coexistence of two phases was not observed. For BLC20 exhibiting a cylindrical structure in both isotropic and liquid crystalline states, the liquid crystalline structure was not smectic but probably nematic, and the spacing was changed continuously in liquid crystallization. No liquid crystallization was observed in SAXS, POM and DSC for BLC15. The orientation of smectic layers within lamellar domains was investigated using 2D-SAXS images. The smectic layer was aligned perpendicularly to the lamellar interface.     

裂齿矩形翅片板翅式换热器优化设计的分析

对裂齿矩形翅片板翅式换热器中的裂齿矩形翅片的传热效率作了分析,并以单位质量材耗的换热能力最大为目标函数,分析研究了在不同雷诺数(Re)的操作条件下裂齿矩形翅片间角度、翅片厚、长度、宽度及极厚之间的关系。结果表明:在气体换热的场合下,当Re在某一范围时翅片可有效地起到强化传热的作用。当板厚为5mm,翅片厚为3mm,翅片间夹角为45°～70°,Re为2×10~3～8×10~3,最佳翅片纵向间距与翅片长度和翅片厚度乘积的平方根的比为1.5～2.5,最佳翅片尺寸系数为3～5时,传热强化效果较好。     

Experience, Context, and the Visual Perception of Human Movement.

Why are human observers particularly sensitive to human movement? Seven experiments examined the roles of visual experience and motor processes in human movement perception by comparing visual sensitivities to point-light displays of familiar, unusual, and impossible gaits across gait-speed and identity discrimination tasks. In both tasks, visual sensitivity to physically possible gaits was superior to visual sensitivity to physically impossible gaits, supporting perception-action coupling theories of human movement perception. Visual experience influenced walker-identity perception but not gait-speed discrimination. Thus, both motor experience and visual experience define visual sensitivity to human movement. An ecological perspective can be used to define the conditions necessary for experience-dependent sensitivity to human movement. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

会计政策选择的效率性分析

会计政策选择类型在理论上大体可分为机会主义型和效率(或有效契约)型。会计政策选择具有效率性,但也为经理人员的机会主义行为打开了大门。在我国,由于企业缺乏一系列有效的激励约束机制,会计政策选择的机会主义仍然严重。为此,必须建立适合我国企业有效的激励约束机制。     

阳平关砂金矿精选厂尾矿综合回收的研究

本文详细的介绍了陕西省阳平关砂金矿精选厂尾矿金和其他可利用的矿物综合回收方法和最佳分选流程。     

注聚采出水分离用动态水力旋流器特性研究

原有的地面工艺和设备已不能满足聚合物驱采出水分离的要求。采用自行研制的动态水力旋流器，在增压与不增压两种工艺流程下，分别进行了流量和转数对分离效率的影响、转数与压力降的关系，以及入口压力与处理量的关系等项试验研究。试验结果表明，与静态水力旋流器相比，动态水力旋流器的分离效率明显提高，一般可提高10％左右；压力损失显著降低，约可减少0．1MPa，足见可在低压下工作，易于实现无泵运行；无泵运行明显比有泵增压运行的分离效率高，但处理量会有所降低。将动态水力旋流器应用于聚合物驱产出水的油－水分离处理是完全可行的。     

低温粉碎系统中旋风分离器设计

旋风分离器是一种应用离心力进行粉体分离的设备。低温粉碎系统应用它分离粉体并起集粉作用。它的效率决定了物质回收率。本文从离心加速度与重力加速度的比值，筒体的高低，筒体直径，进口速度叙述对分离器效率的影响。着重叙述筒体直径确定方法，以及我们设计造长筒形旋风分离器的具体结构和令人满意的试验结果。     

PAA-PSF交联复合膜的制备及对低浓度有机醇水溶液反渗透分离性能研究

进行了ＰＡＡ（ＰｏｌｙａｃｒｙｌｉｃＡｃｉｄ）－ＰＳＦ（Ｐｏｌｙｓｕｌｆｏｎｅ）交联复合膜的制备，研究了交联剂、添加剂对膜性能的影响，并通过扫描电镜观察了膜的断面结构．研究了ＰＡＡ－ＰＳＦ交联复合膜对低浓度有机醇类水溶液反渗透分离性能．发现对于１０００×１０－６乙醇水溶液截留率达到６６．２％，透过流束可达０．９×１０－６（ｍ３·ｍ－２·ｓ－１）．随醇的分子量的增加，截留率不断上升，对戊醇的截留率达９４．３％，而透过流束则保持相对稳定．对不同结构醇类的分离性能研究表明，截留率存在有：ｔｅｒｔ－＞ｓｅｃ－＞ｉｓｏ－＞ｎ－的规律．